Product ID:RP 4033 HARDENER
MSDS Date:11/04/1985
FSC:8030
NIIN:00F000475
Kit Part:Y
MSDS Number: BBGRZ

CIBA GEIGY CORP/PLASTICS & ADDITIVES

THREE SKYLINE DRIVE
HAWTHORNE, NY 10532-2119
US

Emergency Phone: 800-888-8372

Info Phone: 914-785-2000

Cage: EO487

CIBA-GEIGY CORP ADDITIVES DIV.

HAWTHORNE, NY 10532-2119 US

Telephone: 800-888-8372

Cage: 07566

1,3-PHENYLENEDIAMINE

CAS: 108-45-2

RTECS: SS7700000

ACGIH TLV: 0.1 MG/M3; 9394

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

ACGIH TLV: S, 0.1 PPM; A2; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

MENTHANE DIAMINE, CYCLOHEXANEMETHANAMINE, 4-AMINO-ALPHA,

CAS: 80-52-4

RTECS: OS8925000

ISOPHORONE DIAMINE

CAS: 2855-13-2

RTECS: GV6129000

AROMATIC AMINES & EPOXY RESINS ADDUCT *93-1*

CAS: 70703-43-4

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SKIN: CORROSIVE, BURNS, SENSITIZATION,
RASH, DERMATITIS, ABSORPTION. EYES: CORROSIVE, BURNS, IRRITATION.
INHALATION: RESPIRATORY IRRITATION, ASTHMA-LIKE EFFECTS, INJURIOUS
TO MUCOUS MEMBRANES, FEVER, CHILL, ANOREXIA, VOMITING, TRANSIENT
LIVER DAMAGE, CYANOSIS. INGESTION: HARMFUL.
Explanation of Carcinogenicity:PRODUCT CONTAINS MDA (101-77-9) WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Medical Cond Aggravated by Exposure:SKIN & EYE CONDITIONS

First Aid:INHALATION: REMOVE TO FRESH AIR, ADMINISTER ASSISTED
RESPIRATION IF NECESSARY. INGESTION: IF CONSCIOUS, GIVE WATER TO
DRINK. INDUCE VOMITING, CALL PHYSICIAN. SKIN: WASH WITH SOAP AND
WATER. EYES: FLUS H WITH WATER FOR AT LEAST 15 MINUTES. CALL
PHYSICIAN. NOTE: CONTAMINATED CLOTHING SHOULD BE CLEANED OR
REPLACED BEFORE REUSE.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DECOMPOSITION & COMBUSTION PRODUCTS MAY
BE TOXIC.

Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN SAND OR
ABSORBENT SWEEPING COMPOUND, DISPOSE IF IN CSED CONTAINER. FLUSH
CONTAMINATED AREA WITH WATER; COLLECT WATER FOR PROR DISPOSAL.
AVOID CONTACT. CLEANUP PERSONNEL MUST WEAR PROPER PROTECTIVE
EQUIPMENT.

Handling and Storage Precautions:DANGER CANCER SUSPECT AGENT.
PROLONGED OR REPEATED CONTACT OF LIQUID OR BREATHING OF VAPORS OR
DUSTS MAY CAUSE DELAYED OR SERIOUS INJURY.
Other Precautions:AVOID CONTACT W/SKIN, EYES OR CLOTHING & BREATHING OF
VAPOR OR MIST.

Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE
RESPIRATOR WHEN VAPOR/MIST EXPOSURE IS LIKELY.
Ventilation:GENERAL MECHANICAL & LOCAL EXHAUST IN ACCORDANCE W/ACGIH
RECOMMENDATIONS.
Protective Gloves:IMPERMEABLE
Eye Protection:FULL FACE SHIELD
Other Protective Equipment:APPROPRIATE CLOTHING (APRONS, COVERRALLS,
GLOVES, FACE SHIELDS, GOGGLES, ETC) TO PREVENT DERMAL EXPOSURE.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MSDS UPDATED BY DGSC-SSH TO REFLECT OSHA'S MORE STRINGENT STANDARDS FOR
MDA. USER SHOULD CONSULT LOCAL SAFETY OFFICE FOR SPECIFIC DETAILS
OF WORK PRACTICES, MEDICAL SURVEILLANCE AND HOUSEKEEPING PROCE
DURES FOR MDA EXPOSURES.

HCC:T7
Boiling Pt:B.P. Text:>400F,>204C
Vapor Pres:3.3
Vapor Density:>1
Spec Gravity:1.04
Solubility in Water:MODERATE
Appearance and Odor:LIGHT BROWN LIQUID W/SLIGHT AMMONIACAL ODOR.
Percent Volatiles by Volume:<1%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING ACIDS, METAL-ORGANIC COMPOUNDS
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:CO, CO2 & NITROGEN OXIDES

Waste Disposal Methods:CONSULT QUALIFIED LOCAL OR CORPORATE PERSONNEL
FOR METHOD THAT WILL COMPLY WITH LOCAL, STATE AND FEDERAL HEALTH
AND ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.